Step 1: Use the condition that \(\vec{a}\) and \(\vec{b}\) are unit vectors.
Since both \(\vec{a}\) and \(\vec{b}\) are unit vectors, we have:
\[
|\vec{a}|=1 \quad \text{and} \quad |\vec{b}|=1
\]
Step 2: Use the condition given in the question.
It is given that \(\vec{a}-\vec{b}\) is also a unit vector. Therefore:
\[
|\vec{a}-\vec{b}|=1
\]
Step 3: Use the identity for magnitude.
We know that:
\[
|\vec{a}-\vec{b}|^2=|\vec{a}|^2+|\vec{b}|^2-2\vec{a}\cdot\vec{b}
\]
Substituting the given values:
\[
1^2=1^2+1^2-2\vec{a}\cdot\vec{b}
\]
Step 4: Simplify the equation.
\[
1=1+1-2\vec{a}\cdot\vec{b}
\]
\[
1=2-2\vec{a}\cdot\vec{b}
\]
\[
2\vec{a}\cdot\vec{b}=1
\]
\[
\vec{a}\cdot\vec{b}=\frac{1}{2}
\]
Step 5: Use the dot product formula.
We know that:
\[
\vec{a}\cdot\vec{b}=|\vec{a}||\vec{b}|\cos\theta
\]
Since both are unit vectors:
\[
\vec{a}\cdot\vec{b}=\cos\theta
\]
Step 6: Solve for \(\theta\).
\[
\cos\theta=\frac{1}{2}
\]
Thus,
\[
\theta=\frac{\pi}{3}
\]
Step 7: Match with the options.
The value \(\frac{\pi}{3}\) corresponds to option \((1)\). Hence, the correct answer is:
\[
\boxed{\frac{\pi}{3}}
\]