Step 1: Understanding the Concept:
In a rectangle, $\overrightarrow{BD} = \overrightarrow{BA} + \overrightarrow{AD} = -\overrightarrow{AB} + \overrightarrow{AD}$. Compute the magnitude of this diagonal vector.
Step 2: Detailed Explanation:
\[
\overrightarrow{BD} = -\overrightarrow{AB} + \overrightarrow{AD} = -(5\hat{i}+4\hat{j}-3\hat{k}) + (3\hat{i}+2\hat{j}-\hat{k})
\]
\[
= (-5+3)\hat{i} + (-4+2)\hat{j} + (3-1)\hat{k} = -2\hat{i} - 2\hat{j} + 2\hat{k}
\]
\[
|BD| = \sqrt{(-2)^2+(-2)^2+(2)^2} = \sqrt{4+4+4} = \sqrt{12} = 2\sqrt{3}
\]
Step 3: Final Answer:
Length of $BD = 2\sqrt{3}$.