Question:

In van der Waals' equation of state of the gas law, the constant 'b' is a measure of:

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a = attraction; b = bulkiness (volume).
Updated On: Apr 8, 2026
  • intermolecular repulsion
  • intermolecular attraction
  • volume occupied by the molecules
  • intermolecular collisions per unit volume
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The Correct Option is C

Solution and Explanation

Step 1: Concept
The van der Waals' equation is $(p + \frac{a}{V^{2}})(V - b) = RT$.
Step 2: Analysis

Constant 'a' represents intermolecular forces, while 'b' is the volume correction.
Step 3: Conclusion

Constant 'b' arises due to the finite size of the molecules, measuring the excluded volume.
Final Answer: (C)
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