Step 1: Concept
In Hydrogen spectrum, transitions to $n=1$ (Lyman) are UV, to $n=2$ (Balmer) are Visible, and to $n=3, 4, 5$ (Paschen, Brackett, Pfund) are Infrared.
Step 2: Analysis of Options
(A) To $n=1$: UV.
(B) & (C) To $n=2$: Visible.
(D) To $n=3$ (Paschen series): Infrared.
Step 3: Conclusion
The transition $n=5 \to n=3$ falls in the Infrared region.
Final Answer:(D)