In voltammetry, various statements describe its applications, functionality, and operating principles. Let's analyze each option to determine the false statement:
- Technique can be used to analyse organic compounds containing carbonyl groups: Voltammetry is indeed a versatile technique used for analyzing organic compounds, including those with carbonyl groups. This statement is correct.
- Organic solvents cannot be used as aqueous organic mixture in this technique: This statement is false. In certain voltammetric techniques, organic solvents can be mixed with aqueous solutions to analyze specific compounds. Therefore, the correct answer is that this statement is false.
- Immuno sensors are available in voltammetry: Immunosensors, which combine electrochemical detection with biological recognition, are indeed utilized in voltammetry to detect various substances. This statement is correct.
- Triangular waveform is used for excitation of solution in cyclic voltammetry: In cyclic voltammetry, the potential of the working electrode is cycled by applying a triangular waveform. Hence, this statement is correct.
The false statement is: Organic solvents cannot be used as aqueous organic mixture in this technique. This indicates that contrary to the statement, organic solvents can be mixed with aqueous solutions in voltammetric techniques.