Step 1: Set up a coordinate system and define vectors.
Let $A$ be the origin $(0,0)$, and place $\vec{AB}$ along the positive x-axis.
From the given ratios, let $15|AC| = 5|AD| = 3|AB| = k$. Then $|AB| = k/3$, $|AD| = k/5$, $|AC| = k/15$. Choose $k = 15$, giving:
\[
|AB| = 5, |AD| = 3, |AC| = 1.
\]
Then $\vec{AB} = 5\vec{i}$.
Angle at $A$ is $\angle A = 2\pi/3 = 120^\circ$, and $AC$ is the bisector, so
\[
\angle BAC = \angle CAD = 60^\circ.
\]
Hence, $\vec{AC} = 1(\cos 60^\circ \vec{i} + \sin 60^\circ \vec{j}) = \frac{1}{2}\vec{i} + \frac{\sqrt{3}}{2}\vec{j}$.
Step 2: Find $\vec{BC$.}
\[
\vec{BC} = \vec{AC} - \vec{AB} = \left(\frac{1}{2}-5\right)\vec{i} + \frac{\sqrt{3}}{2}\vec{j} = -\frac{9}{2}\vec{i} + \frac{\sqrt{3}}{2}\vec{j}.
\]
Step 3: Find the angle between $\vec{AB$ and $\vec{BC}$.}
The angle $\theta$ between vectors is given by:
\[
\cos\theta = \frac{\vec{AB}\cdot\vec{BC}}{|\vec{AB}||\vec{BC}|}.
\]
Compute the dot product:
\[
\vec{AB}\cdot\vec{BC} = (5\vec{i}) \cdot \left(-\frac{9}{2}\vec{i} + \frac{\sqrt{3}}{2}\vec{j}\right) = -\frac{45}{2}.
\]
Magnitudes:
\[
|\vec{AB}| = 5, |\vec{BC}| = \sqrt{\left(-\frac{9}{2}\right)^2 + \left(\frac{\sqrt{3}}{2}\right)^2} = \sqrt{21}.
\]
Thus,
\[
\cos\theta = \frac{-45/2}{5\sqrt{21}} = -\frac{9}{2\sqrt{21}}.
\]
Step 4: Adjust for acute angle.
The question options are positive, implying the acute angle between the vectors. So take
\[
|\cos\theta| = \frac{9}{2\sqrt{21}}.
\]
Rationalize to match the options:
\[
\frac{9}{2\sqrt{21}} = \frac{9}{2\sqrt{3}\sqrt{7}} = \frac{3\sqrt{3}}{2\sqrt{7}}.
\]
Step 5: Conclusion.
Hence, the angle between $\vec{AB}$ and $\vec{BC}$ is:
\[
\boxed{\cos^{-1}\left(\frac{3\sqrt{3}}{2\sqrt{7}}\right)}.
\]