Step 1: Find the normal vector to the plane $\pi_1$.
A normal vector $\vec{n_1}$ to plane $\pi_1$ is perpendicular to both vectors lying in it. We can find it using the cross product.
Let $\vec{u} = \vec{i}+\vec{j}$ and $\vec{v} = \vec{i}+2\vec{j}$.
$\vec{n_1} = \vec{u} \times \vec{v} = (\vec{i}+\vec{j}) \times (\vec{i}+2\vec{j}) = \vec{i}\times\vec{i} + 2\vec{i}\times\vec{j} + \vec{j}\times\vec{i} + 2\vec{j}\times\vec{j}$.
$= \vec{0} + 2\vec{k} - \vec{k} + \vec{0} = \vec{k}$.
Step 2: Find the normal vector to the plane $\pi_2$.
A normal vector $\vec{n_2}$ to plane $\pi_2$ is perpendicular to both vectors lying in it.
Let $\vec{p} = 2\vec{i}-\vec{j}$ and $\vec{q} = 3\vec{i}+2\vec{k}$.
$\vec{n_2} = \vec{p} \times \vec{q} = \begin{vmatrix} \vec{i} & \vec{j} & \vec{k}
2 & -1 & 0
3 & 0 & 2 \end{vmatrix} = \vec{i}(-2) - \vec{j}(4) + \vec{k}(3) = -2\vec{i}-4\vec{j}+3\vec{k}$.
Step 3: Find the direction vector of the line of intersection.
The line of intersection of two planes is perpendicular to both of their normal vectors.
Therefore, a direction vector $\vec{a}$ for this line is parallel to the cross product of the normal vectors, $\vec{n_1} \times \vec{n_2}$.
$\vec{a}$ is parallel to $\vec{k} \times (-2\vec{i}-4\vec{j}+3\vec{k}) = -2(\vec{k}\times\vec{i}) - 4(\vec{k}\times\vec{j}) + 3(\vec{k}\times\vec{k})$.
$= -2(\vec{j}) - 4(-\vec{i}) + \vec{0} = 4\vec{i}-2\vec{j}$.
We can take $\vec{a} = 4\vec{i}-2\vec{j}$ or any scalar multiple, like $2\vec{i}-\vec{j}$. Let's use $\vec{a} = 4\vec{i}-2\vec{j}$.
Step 4: Calculate the angle $\theta$ between $\vec{a$ and the given vector.}
Let $\vec{b} = \vec{i}-2\vec{j}+2\vec{k}$. The angle $\theta$ between $\vec{a}$ and $\vec{b}$ is given by $\cos\theta = \frac{\vec{a} \cdot \vec{b}}{|\vec{a}| |\vec{b}|}$.
$\vec{a} \cdot \vec{b} = (4)(1) + (-2)(-2) + (0)(2) = 4 + 4 = 8$.
$|\vec{a}| = \sqrt{4^2 + (-2)^2} = \sqrt{16+4} = \sqrt{20} = 2\sqrt{5}$.
$|\vec{b}| = \sqrt{1^2 + (-2)^2 + 2^2} = \sqrt{1+4+4} = \sqrt{9} = 3$.
$\cos\theta = \frac{8}{(2\sqrt{5})(3)} = \frac{8}{6\sqrt{5}} = \frac{4}{3\sqrt{5}}$.
Step 5: Ensure the angle is acute.
The value of $\cos\theta = \frac{4}{3\sqrt{5}}$ is positive. Since $\cos\theta$ is positive, the angle $\theta$ must be acute (in the first quadrant). If the dot product had been negative, we would have taken the vector $-\vec{a}$ to ensure an acute angle, but it's not necessary here.
Thus, $\theta = \cos^{-1}(\frac{4}{3\sqrt{5}})$. This matches option (C).