Step 1: Use the condition \(p=q\).
Since
\[
p+q=1
\]
and
\[
p=q,
\]
we get
\[
p=q=\frac12.
\]
Step 2: Write the binomial probability.
For a binomial distribution,
\[
P(X=r)
=
{}^{n}C_{r}p^{r}q^{\,n-r}.
\]
Therefore,
\[
P(X=5)
=
{}^{n}C_{5}
\left(\frac12\right)^5
\left(\frac12\right)^{n-5}.
\]
\[
P(X=5)
=
{}^{n}C_{5}
\left(\frac12\right)^n.
\]
Step 3: Multiply by \(2^n\).
\[
2^nP(X=5)
=
2^n\cdot
{}^{n}C_{5}
\left(\frac12\right)^n.
\]
\[
=
{}^{n}C_{5}.
\]
Step 4: Final conclusion.
Hence,
\[
\boxed{{}^{n}C_{5}}
\]