Concept:
The representative fraction (RF) of a map is
\[
\boxed{\text{RF}=\frac{\text{Map Distance}}{\text{Ground Distance}}}
\]
For a scale of
\[
1:100000
\]
it means
\[
1\text{ cm on map}=100000\text{ cm on ground}.
\]
Step 1: Convert ground distance into metres.
Since
\[
100\text{ cm}=1\text{ m},
\]
\[
100000\text{ cm}
=\frac{100000}{100}
=1000\text{ m}.
\]
Step 2: Convert metres into kilometres.
Since
\[
1000\text{ m}=1\text{ km},
\]
therefore
\[
1\text{ cm on map}=1\text{ km on ground}.
\]
Hence,
\[
\boxed{1\text{ cm}=1\text{ km}}
\]
Therefore, the correct option is
\[
\boxed{(A).}
\]