Concept:
If
\[
X\sim\text{Poisson}(\lambda),
\]
then
\[
P(X=x)
=
\frac{e^{-\lambda}\lambda^x}{x!},
\]
and
\[
\boxed{\text{Mean}=\text{Variance}=\lambda.}
\]
Step 1: Use \(P(X=0)\).
For \(x=0\),
\[
P(X=0)
=
e^{-\lambda}.
\]
Given,
\[
e^{-\lambda}=0.8=\frac45.
\]
Step 2: Find \(\lambda\).
Taking logarithm,
\[
-\lambda
=
\ln\frac45.
\]
Hence,
\[
\lambda
=
-\ln\frac45
=
\ln\frac54.
\]
Since variance equals \(\lambda\),
\[
\boxed{
\operatorname{Var}(X)
=
\ln\frac54.
}
\]
Therefore, the correct option is
\[
\boxed{(B).}
\]