Step 1: Compare with the general equation of pair of lines.
The general second degree equation is
\[
Ax^2+2Hxy+By^2+2Gx+2Fy+C=0
\]
Given,
\[
9x^2+axy+4y^2+6x+by-3=0
\]
Comparing coefficients,
\[
A=9,\qquad 2H=a,\qquad B=4
\]
\[
2G=6 \Rightarrow G=3
\]
\[
2F=b \Rightarrow F=\frac{b}{2}
\]
\[
C=-3
\]
Step 2: Condition for parallel lines.
For the equation to represent two parallel straight lines,
\[
H^2=AB
\]
Since
\[
H=\frac{a}{2},
\]
we get
\[
\left(\frac{a}{2}\right)^2=(9)(4)
\]
\[
\frac{a^2}{4}=36
\]
\[
a^2=144
\]
\[
a=\pm12
\]
Step 3: Use the determinant condition.
For parallel lines, the determinant condition is
\[
\Delta=
ABC+2FGH-AF^2-BG^2-CH^2=0
\]
Substitute the values:
\[
(9)(4)(-3)
+
2\left(3\right)\left(\frac{b}{2}\right)\left(\frac{a}{2}\right)
-
9\left(\frac{b}{2}\right)^2
-
4(3)^2
-
(-3)\left(\frac{a}{2}\right)^2
=0
\]
Simplifying,
\[
-108+\frac{3ab}{2}-\frac{9b^2}{4}-36+\frac{3a^2}{4}=0
\]
Now use
\[
a^2=144
\]
\[
-108+\frac{3ab}{2}-\frac{9b^2}{4}-36+108=0
\]
\[
\frac{3ab}{2}-\frac{9b^2}{4}-36=0
\]
Multiply by \(4\),
\[
6ab-9b^2-144=0
\]
Divide by \(3\),
\[
2ab-3b^2-48=0
\]
Step 4: Check the options.
For
\[
a=12,\qquad b=4,
\]
\[
2(12)(4)-3(4)^2-48
\]
\[
96-48-48=0
\]
Hence, the condition is satisfied.
For
\[
a=-12,\qquad b=4,
\]
\[
2(-12)(4)-48-48\neq0
\]
Thus this is not possible.
Therefore,
\[
a=12,\qquad b=4
\]
Step 5: Final conclusion.
Hence,
\[
\boxed{a=12,\; b=4}
\]
which corresponds to option (2).