Concept:
Ellipse relations:
\[
e = \frac{c}{a}, \quad c^2 = a^2 - b^2
\]
Step 1: Use given condition.
\[
2a = 3(2b) \Rightarrow a = 3b
\]
Step 2: Find eccentricity.
\[
c^2 = a^2 - b^2 = 9b^2 - b^2 = 8b^2
\]
\[
c = 2\sqrt{2}b
\]
\[
e = \frac{c}{a} = \frac{2\sqrt{2}b}{3b} = \frac{2\sqrt{2}}{3}
\]