Concept:
For a standard ellipse centered at the origin with its major axis along the x-axis, the coordinates of the vertices are $(\pm a, 0)$ and the coordinates of the foci are $(\pm ae, 0)$, where $a$ is the semi-major axis and $e$ is the eccentricity.
Step 1: Identify the values from the given coordinates.
The vertices are given as $(\pm 3, 0)$. By comparing this to the standard form $(\pm a, 0)$, we get:
$$a = 3$$
The foci are given as $(\pm 2, 0)$. By comparing this to the standard form $(\pm ae, 0)$, we get:
$$ae = 2$$
Step 2: Solve for the eccentricity (e).
Substitute the value of $a = 3$ into the foci equation:
$$(3)e = 2$$
$$e = \frac{2}{3}$$