Step 1: Concept
Use the identity $\tan^{-1} a + \tan^{-1} b + \tan^{-1} c = \tan^{-1} \left( \frac{a+b+c-abc}{1-ab-bc-ca} \right)$.
Step 2: Meaning
Since the sum is $\pi/2$, the tangent of the sum is undefined, meaning the denominator must be zero.
Step 3: Analysis
Let $a = x/2, b = y/2, c = z/2$.
$1 - (ab + bc + ca) = 0 \implies ab + bc + ca = 1$.
$\frac{x}{2}\frac{y}{2} + \frac{y}{2}\frac{z}{2} + \frac{z}{2}\frac{x}{2} = 1$.
$\frac{xy + yz + zx}{4} = 1$.
Step 4: Conclusion
$xy + yz + zx = 4$.
Final Answer: (D)