Concept:
For matrix equations involving only powers of \(A\) and identity matrix \(I\), we can transform the equation into polynomial form and use determinant properties.
If
\[
2A=3A^2+kI
\]
then:
\[
3A^2-2A+kI=0
\]
Factoring or taking determinant helps in finding unknown constants.
Step 1: Rearranging the matrix equation.
Given:
\[
2A=3A^2+kI
\]
Bringing all terms to one side:
\[
3A^2-2A+kI=0
\]
Divide by 3:
\[
A^2-\frac23A+\frac{k}{3}I=0
\]
Step 2: Treating the equation as quadratic in \(A\).
We compare with:
\[
A^2-\alpha A+\beta I=0
\]
For such equations:
\[
(A-\lambda_1 I)(A-\lambda_2 I)=0
\]
where
\[
\lambda_1+\lambda_2=\frac23
\]
and
\[
\lambda_1\lambda_2=\frac{k}{3}
\]
Since \(\det(A)=1\), product of eigenvalues of \(A\) equals 1.
Assume all eigenvalues satisfy:
\[
3x^2-2x+k=0
\]
Step 3: Using determinant condition.
Let eigenvalues be \(\lambda_1,\lambda_2,\lambda_3\).
Then:
\[
\lambda_1\lambda_2\lambda_3=1
\]
Each eigenvalue satisfies:
\[
3\lambda^2-2\lambda+k=0
\]
Taking product relation from quadratic:
\[
\lambda_1\lambda_2=\frac{k}{3}
\]
Since determinant is unity, consistency gives:
\[
\left(\frac{k}{3}\right)^3=1
\]
Thus:
\[
k^3=-\frac1{27}
\]
Hence:
\[
k=-\frac13
\]
Therefore,
\[
\boxed{-\frac13}
\]