Step 1: Concept
\(A^T\) is the transpose of matrix \(A\). The sum \(A + A^T\) is compared with the identity matrix \(I\).
Step 2: Matrix Representation
\[ A^T = \begin{bmatrix} \sin\alpha & \cos\alpha \\ -\cos\alpha & \sin\alpha \end{bmatrix} \]
Therefore, \[ A + A^T = \begin{bmatrix} 2\sin\alpha & 0 \\ 0 & 2\sin\alpha \end{bmatrix} \]
Since \(A + A^T = I\), \[ \begin{bmatrix} 2\sin\alpha & 0 \\ 0 & 2\sin\alpha \end{bmatrix} = \begin{bmatrix} 1 & 0 \\ 0 & 1 \end{bmatrix} \]
Step 3: Analysis
Equating corresponding elements: \[ 2\sin\alpha = 1 \]
Therefore, \[ \sin\alpha = \frac{1}{2} \]
In the interval: \[ \left(\frac{\pi}{2}, \frac{3\pi}{2}\right) \] sine is positive only in the second quadrant.
Step 4: Conclusion
The required angle is: \[ \alpha = \pi - \frac{\pi}{6} = \frac{5\pi}{6} \]
Final Answer: \[ \boxed{\frac{5\pi}{6}} \] Hence, the correct option is (B).