Step 1: Find the slope of diagonal \(AC\).
The points are
\[
A(-3,3)
\]
and
\[
C(1,-1)
\]
Slope of \(AC\) is
\[
m_1=\frac{-1-3}{1-(-3)}
\]
\[
m_1=\frac{-4}{4}
\]
\[
m_1=-1
\]
Step 2: Find the slope of diagonal \(BD\).
The points are
\[
B(1,1)
\]
and
\[
D(-2,-2)
\]
Slope of \(BD\) is
\[
m_2=\frac{-2-1}{-2-1}
\]
\[
m_2=\frac{-3}{-3}
\]
\[
m_2=1
\]
Step 3: Check perpendicularity of diagonals.
Two lines are perpendicular if
\[
m_1m_2=-1
\]
Here,
\[
m_1m_2=(-1)(1)
\]
\[
m_1m_2=-1
\]
Therefore, diagonals \(AC\) and \(BD\) are perpendicular.
Step 4: Find the angle between the diagonals.
Since the diagonals are perpendicular, the angle between them is
\[
\frac{\pi}{2}
\]
Step 5: Final conclusion.
Hence, the required angle is
\[
\boxed{\frac{\pi}{2}}
\]