Step 1: Understanding the Concept
Thermoplastic polymers are linear or slightly branched polymers that soften on heating and harden on cooling, so they can be reshaped repeatedly. Thermosetting polymers form cross-links and cannot be remoulded.
Step 2: Check Each Option
Urea formaldehyde resin is thermosetting.
Polystyrene is thermoplastic.
Nylon 6,6 is classed as a fibre.
Vulcanised rubber is cross-linked with sulphur.
Step 3: Compare the options
Polystyrene is option (B).
Final Answer:
Polystyrene is the thermoplastic polymer.
\[ \boxed{\text{(B) }\text{Polystyrene}} \]