Question:

Identify the reagent 'R' necessary to bring the following conversion.

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Key reaction: Acid chloride + H$_2$O → Carboxylic acid
Updated On: May 8, 2026
  • $\text{H}_2\text{O}$
  • $\text{CrO}_3$
  • $\text{NaOH}$ (dil.)
  • $\text{KMnO}_4$
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The Correct Option is A

Solution and Explanation



Step 1: Identify reaction

The given conversion is: \[ \text{Benzoyl chloride} \rightarrow \text{Benzoic acid} \]

Step 2: Reaction type

This is hydrolysis of acid chloride. Acid chlorides react with water to give corresponding carboxylic acid: \[ \text{R-COCl} + \text{H}_2\text{O} \rightarrow \text{R-COOH} + \text{HCl} \]

Step 3: Apply to given compound

\[ \text{C}_6\text{H}_5\text{COCl} + \text{H}_2\text{O} \rightarrow \text{C}_6\text{H}_5\text{COOH} \]

Step 4: Check options


• $\text{H}_2\text{O}$ → Hydrolysis \checkmark
• $\text{CrO}_3$ → Oxidizing agent $\times$
• NaOH → Gives salt first (not direct acid) $\times$
• KMnO$_4$ → Strong oxidizing agent $\times$ Conclusion:
Required reagent is water. Final Answer: Option (A)
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