Question:

Identify the product 'A' in the following reaction.

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Hypophosphorous acid replaces the diazonium group with hydrogen, giving benzene.
Updated On: Nov 12, 2026
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the Concept
The reactant is benzenediazonium chloride, \(\text{C}_6\text{H}_5\text{N}_2^+\text{Cl}^-\).

Step 2: Reagent
Mild reducing agents such as hypophosphorous acid (\(\text{H}_3\text{PO}_2\)) with water replace the diazonium group by hydrogen.

Step 3: Reaction
\(\text{C}_6\text{H}_5\text{N}_2\text{Cl}+\text{H}_3\text{PO}_2+\text{H}_2\text{O}\rightarrow\text{C}_6\text{H}_6+\text{N}_2+\text{H}_3\text{PO}_3+\text{HCl}\).

Step 4: Compare the options
The product A is benzene, option (D). Option (A) is benzonitrile, which would need CuCN.

Final Answer:
Product A is benzene. \[ \boxed{\text{(D) }\text{benzene}} \]
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