Step 1: Understanding the Concept
A mixed (unsymmetrical) ketone has two different groups attached to the carbonyl group.
Step 2: Check each ketone
Butanone: \(\text{CH}_{3}\text{COC}_{2}\text{H}_{5}\), mixed.
Acetophenone: \(\text{C}_{6}\text{H}_{5}\text{COCH}_{3}\), mixed.
Acetone and benzophenone have identical groups, so they are simple ketones.
Step 3: Conclusion
Both members of the pair are mixed ketones only in butanone with acetophenone.
Final Answer:
Butanone and acetophenone are both mixed ketones.
\[ \boxed{\text{(B) }\text{Butanone, acetophenone}} \]