Step 1: Understanding the Concept
Oxides of electropositive metals such as Ca and Na are basic. Oxides of non-metals are acidic or neutral.
Step 2: Check each pair
CaO and \(\text{Na}_2\text{O}\): both metal oxides, so both are basic.
\(\text{SO}_2\) and \(\text{Cl}_2\text{O}\): both acidic.
BaO and \(\text{N}_2\text{O}_5\): BaO is basic but \(\text{N}_2\text{O}_5\) is acidic.
CO and \(\text{N}_2\text{O}\): both neutral.
Step 3: Result
Only the first pair has two basic oxides.
Final Answer:
The pair of basic oxides is CaO and Na2O, which is option (A).
\[ \boxed{\text{(A) }\text{CaO and Na}_{2}\text{O}} \]