Step 1: Understanding the Concept
Breathing apparatus needs a compound that removes exhaled \(\text{CO}_2\) and supplies \(\text{O}_2\) together.
Step 2: Reaction
Potassium superoxide reacts with carbon dioxide: \(4\text{KO}_2+2\text{CO}_2\rightarrow2\text{K}_2\text{CO}_3+3\text{O}_2\).
Step 3: Why the other options fail
The normal oxides \(\text{Na}_2\text{O}\) and \(\text{K}_2\text{O}\) and the peroxide \(\text{Na}_2\text{O}_2\) are not used for this dual role.
Final Answer:
The oxide is \(\text{KO}_2\).
\[ \boxed{\text{(D) }\text{KO}_{2}} \]