Step 1: Understanding the Concept
Natural rubber is cis-1,4-polyisoprene, a polymer of a diene.
Step 2: Monomer
Its repeating unit comes from isoprene, 2-methylbuta-1,3-diene, \(\text{CH}_2=\text{C(CH}_3)-\text{CH}=\text{CH}_2\).
Step 3: Other options
Acrylonitrile gives PAN, caprolactam gives nylon 6 and tetrafluoroethylene gives Teflon. All three are synthetic polymers.
Final Answer:
The monomer of natural rubber is isoprene.
\[ \boxed{\text{(B) }\text{Isoprene}} \]