Concept:
Natural rubber is a polymer formed by repeated addition of isoprene units.
Its polymer is called cis-1,4-polyisoprene.
Step 1: Recall the monomer of natural rubber.
Natural rubber is obtained from:
\[
\text{isoprene}
\]
Its structure is:
\[
\text{CH}_2 = \text{C}(\text{CH}_3)-\text{CH}=\text{CH}_2
\]
Step 2: Eliminate the other options.
• Polyacrylonitrile is itself a polymer.
• Chloroprene is the monomer of neoprene.
• Tetrafluoroethylene is the monomer of Teflon.
Hence, the correct answer is:
\[
\boxed{(A)\ \text{Isoprene}}
\]