Step 1: Concept
A tertiary ($3^{\circ}$) amine has three carbon atoms directly attached to the nitrogen atom (no H atoms on N).
Step 2: Analysis
- (A) is a primary amine ($R-NH_{2}$).
- (B) consists of two primary amine groups.
- (C) is a secondary amine ($R_{2}NH$).
- (D) has three alkyl groups (Ethyl, Methyl, and Isopropyl) on the Nitrogen.
Step 3: Conclusion
Hence, (D) is the tertiary amine.
Final Answer: (D)