Question:

Identify best method for preparation of Alkyl fluoride from following

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Alkyl fluorides are made by halogen exchange with a metallic fluoride.
Updated On: Nov 12, 2026
  • Finkelstein reaction
  • Swartz reaction
  • Sandmeyer's reaction
  • Wurtz reaction
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The Correct Option is B

Solution and Explanation

Step 1: Understanding the Concept
Direct fluorination is too violent, so alkyl fluorides are made by halogen exchange. An alkyl chloride or bromide is heated with a metallic fluoride such as AgF or \(\text{Hg}_2\text{F}_2\).

Step 2: Name the reaction
This halogen exchange is the Swarts reaction.

Step 3: Other options
Finkelstein reaction (NaI in acetone) gives alkyl iodides. Sandmeyer gives aryl halides, and Wurtz joins alkyl halides to alkanes.

Final Answer:
The best method is the Swarts reaction. \[ \boxed{\text{(B) }\text{Swartz reaction}} \]
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