Step 1: Understanding the Concept
Dipole moment depends on bond polarity and on molecular shape. Bond dipoles can cancel in a symmetric shape.
Step 2: Detailed Explanation
BeF\(_2\) is linear, so the two Be-F dipoles cancel and the moment is zero.
CHCl\(_3\) is tetrahedral and the three C-Cl dipoles partly cancel, giving about 1.0 D.
NH\(_3\) is pyramidal with a lone pair, giving about 1.47 D.
H\(_2\)O is bent with two lone pairs and very polar O-H bonds, giving about 1.85 D, the highest of the four.
Final Answer:
Water has the highest dipole moment, option (B).
\[ \boxed{\text{H}_2\text{O (B)}} \]