Question:

Identify 'A' in the following reaction.

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Remember: \[ \text{Salicylic acid} + \text{Acetic anhydride} \rightarrow \text{Aspirin} \] Aspirin is also called Acetylsalicylic acid.
Updated On: May 8, 2026
  • Acrylic acid
  • Oxalic acid
  • Salicylic acid
  • Phthalic acid
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The Correct Option is C

Solution and Explanation


Concept: Aspirin is chemically known as Acetylsalicylic acid. It is prepared by the acetylation of salicylic acid using acetic anhydride in the presence of an acid catalyst.
• Salicylic acid contains a phenolic \((-OH)\) group.
• Acetic anhydride provides the acetyl group \((CH_3CO-)\).
• The reaction produces aspirin and acetic acid.

Step 1:
Identify the product formed.
The product given in the reaction is: \[ \text{Aspirin} \] Aspirin is chemically known as: \[ \text{Acetylsalicylic acid} \] Hence, the reactant must be: \[ \text{Salicylic acid} \]

Step 2:
Write the reaction involved. \[ \text{Salicylic acid} + \text{Acetic anhydride} \xrightarrow{H^+} \text{Aspirin} + \text{Acetic acid} \]

Step 3:
Eliminate incorrect options.
Acrylic acid does not form aspirin on acetylation.
Oxalic acid is a dicarboxylic acid and is not used in aspirin synthesis.
Phthalic acid also does not produce aspirin with acetic anhydride.

Step 4:
Conclusion.
Therefore, compound \(A\) is: \[{\text{Salicylic acid}} \] Final Answer: Option (C)
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