Question:

How many moles of iodomethane are consumed in the following conversion?
$\text{CH}_3\text{NH}_2 \xrightarrow[\Delta]{\text{CH}_3\text{I}} (\text{CH}_3)_4\text{N}^+ \text{I}^-$}

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Rule: Primary amine $\rightarrow$ quaternary ammonium needs 3 alkylations
Updated On: May 8, 2026
  • Four
  • Three
  • Two
  • One
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The Correct Option is B

Solution and Explanation


Concept: Alkylation of amines proceeds stepwise.

Step 1:
Track methylation.
• $\text{CH}_3\text{NH}_2 \rightarrow (\text{CH}_3)_2\text{NH}$ (1 mole CH$_3$I)
• $\rightarrow (\text{CH}_3)_3\text{N}$ (2 moles CH$_3$I total)
• $\rightarrow (\text{CH}_3)_4\text{N}^+$ (3 moles CH$_3$I total)

Step 2:
Conclusion.
Total iodomethane required = 3 moles. Final Answer: Option (B)
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