Step 1: Understanding the problem.
The given heat of formation for H\(_2\)O is -270 kJ mol\(^{-1}\), which represents the heat released when 1 mole of H\(_2\)O is formed. We need to calculate the amount of water that can be decomposed by 675 kJ of heat.
Step 2: Calculation.
First, calculate the moles of H\(_2\)O that can be decomposed:
\[
\text{Moles of H}_2\text{O} = \frac{675 \, \text{kJ}}{270 \, \text{kJ/mol}} = 2.5 \, \text{mol}
\]
Now, use the molar mass of water (18 g/mol) to find the mass of water:
\[
\text{Mass of H}_2\text{O} = 2.5 \, \text{mol} \times 18 \, \text{g/mol} = 45 \, \text{g}
\]
Step 3: Conclusion.
The correct answer is (A) 45 g, as 675 kJ of heat will decompose 45 g of water.