Step 1: Understanding the Concept
Neuroglia are supporting cells of the nervous system, and each type has its own job.
Step 2: Match the job
Astrocytes are star-shaped and their end feet wrap the brain capillaries, helping to form and maintain the blood-brain barrier.
Step 3: Why the others fail
Ependymal cells line the ventricles, microglia are phagocytic defence cells, and oligodendrocytes form myelin in the CNS.
Final Answer:
Astrocytes maintain the blood-brain barrier.
\[ \boxed{\text{(C) }\text{astrocytes}} \]