We are given the equation:
\[
|\vec{a} + \vec{b}| = |\vec{a} - \vec{b}|
\]
Squaring both sides of the equation to eliminate the magnitudes:
\[
|\vec{a} + \vec{b}|^2 = |\vec{a} - \vec{b}|^2
\]
\[
(\vec{a} + \vec{b}) \cdot (\vec{a} + \vec{b}) = (\vec{a} - \vec{b}) \cdot (\vec{a} - \vec{b})
\]
Expanding both sides:
\[
\vec{a} \cdot \vec{a} + 2 \vec{a} \cdot \vec{b} + \vec{b} \cdot \vec{b} = \vec{a} \cdot \vec{a} - 2 \vec{a} \cdot \vec{b} + \vec{b} \cdot \vec{b}
\]
Simplifying:
\[
2 \vec{a} \cdot \vec{b} = -2 \vec{a} \cdot \vec{b}
\]
\[
4 \vec{a} \cdot \vec{b} = 0
\]
\[
\vec{a} \cdot \vec{b} = 0
\]
Since the dot product \( \vec{a} \cdot \vec{b} = 0 \), this means that the vectors \( \vec{a} \) and \( \vec{b} \) are perpendicular.
Thus, the correct answer is:
\[
\boxed{\vec{a} \perp \vec{b}}
\]