Match the following:
| List-I (Metal in drinking water) | List-II (Maximum prescribed concentration in ppm) |
|---|---|
| A) Mn | I) \( 0.05 \) |
| B) Zn | II) \( 3.0 \) |
| C) Cd | III) \( 0.005 \) |
| D) Cu | IV) \( 5.0 \) |
The heat generated in 1 minute between points A and B in the given circuit, when a battery of 9 V with internal resistance of 1 \(\Omega\) is connected across these points is ______ J. 
The given circuit works as: 