Concept:
An
adiabatic process is a thermodynamic process in which no heat is exchanged between the system and its surroundings.
\[
Q = 0
\]
For an ideal gas undergoing an adiabatic process, the relation between pressure and volume is given by
\[
PV^\gamma = \text{constant}
\]
where
- \(P\) = pressure
- \(V\) = volume
- \(\gamma = \frac{C_p}{C_v}\) = adiabatic index
Step 1: Use the first law of thermodynamics.}
\[
dQ = dU + dW
\]
For adiabatic process
\[
dQ = 0
\]
\[
dU = -dW
\]
Step 2: Derive the pressure–volume relation.}
Using ideal gas relations and thermodynamic identities, the final relation becomes
\[
PV^\gamma = \text{constant}
\]
Step 3: Interpretation.}
During adiabatic expansion, volume increases and pressure decreases more rapidly compared to an isothermal process.
Thus, the correct relation is
\[
PV^\gamma = \text{constant}
\]