Step 1: Relation between \(C_v\) and degrees of freedom.
For an ideal gas,
\[
C_v = \frac{f}{2}R,
\]
where \(f\) is the number of degrees of freedom. Step 2: Using the given ratio.
\[
\frac{R}{C_v} = \frac{2}{f}.
\]
Given
\[
\frac{R}{C_v} = 0.67 \approx \frac{2}{3}.
\] Step 3: Determining degrees of freedom.
\[
\frac{2}{f} = \frac{2}{3} \Rightarrow f = 3.
\] Step 4: Identifying the gas.
A gas with 3 degrees of freedom is monoatomic. Step 5: Conclusion.
The gas is monoatomic.