Concept:
Vapour density (VD) is related to molar mass as:
\[
\text{Molar mass} = 2 \times VD
\]
At STP, one mole of gas occupies \(22.4\) L.
Step 1: Find molar mass of the gas.
\[
M = 2 \times 16 = 32
\]
Step 2: Find number of moles.
\[
n = \frac{\text{given mass}}{\text{molar mass}}
\]
\[
n = \frac{8}{32} = 0.25
\]
Step 3: Calculate volume at STP.
\[
V = n \times 22.4
\]
\[
V = 0.25 \times 22.4
\]
\[
V = 5.6 \text{ L}
\]
Thus, the volume occupied is \(5.6\) L.