The scalar triple product of three vectors \( \vec{a}, \vec{b}, \vec{c} \) is given by:
\[
\vec{a} \cdot (\vec{b} \times \vec{c})
\]
It represents the volume of the parallelepiped formed by the vectors \( \vec{a}, \vec{b}, \vec{c} \).
For the unit vectors \( \hat{i}, \hat{j}, \hat{k} \), the cross product \( \hat{j} \times \hat{k} \) results in \( \hat{i} \) (from the right-hand rule and the cyclic property of unit vectors):
\[
\hat{j} \times \hat{k} = \hat{i}
\]
Now, taking the dot product of \( \hat{i} \) with \( \hat{i} \):
\[
\hat{i} \cdot \hat{i} = 1
\]
Thus, the value of the scalar triple product is:
\[
\boxed{1}
\]