Question:
[Fe(H\(_2\)O)\(_5\)(ONO)]Cl and [Fe(H\(_2\)O)\(_5\)(NO\(_2\))]Cl are the examples of
[Fe(H\(_2\)O)\(_5\)(ONO)]Cl and [Fe(H\(_2\)O)\(_5\)(NO\(_2\))]Cl are the examples of
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Common ambidentate ligands include NO\(_2^-\) (N or O), CN\(^-\) (C or N), and SCN\(^-\) (S or N).
Updated On: Apr 24, 2026
- Solvate isomerism
- Geometrical isomerism
- Linkage isomerism
- Ionisation isomerism
- Coordination isomerism
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The Correct Option is C
Solution and Explanation
Step 1: Understanding the Concept:
Linkage isomerism arises when an ambidentate ligand can coordinate to the metal center through two different donor atoms.
Step 2: Detailed Explanation:
The two complexes differ in the point of attachment of the NO\(_2\) group. In the first complex, [Fe(H\(_2\)O)\(_5\)(ONO)]Cl, the ligand is coordinated through the oxygen atom (nitrito-O). In the second complex, [Fe(H\(_2\)O)\(_5\)(NO\(_2\))]Cl, the same ligand is coordinated through the nitrogen atom (nitro-N). This is a classic example of linkage isomerism.
Step 3: Final Answer:
These are examples of linkage isomerism.
Linkage isomerism arises when an ambidentate ligand can coordinate to the metal center through two different donor atoms.
Step 2: Detailed Explanation:
The two complexes differ in the point of attachment of the NO\(_2\) group. In the first complex, [Fe(H\(_2\)O)\(_5\)(ONO)]Cl, the ligand is coordinated through the oxygen atom (nitrito-O). In the second complex, [Fe(H\(_2\)O)\(_5\)(NO\(_2\))]Cl, the same ligand is coordinated through the nitrogen atom (nitro-N). This is a classic example of linkage isomerism.
Step 3: Final Answer:
These are examples of linkage isomerism.
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