Step 1: Understanding chlorophyll structure.
Chlorophyll–a is the primary photosynthetic pigment present in green plants and contains magnesium at its centre.
Step 2: Identifying correct formula.
The accepted empirical formula of chlorophyll–a is C$_{55}$H$_{72}$O$_5$N$_4$Mg.
Step 3: Conclusion.
Therefore, the correct answer is C$_{55$H$_{72}$O$_5$N$_4$Mg}.