Question:

Decarboxylation of sodium propionate leads to the formation of

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The general reaction: \(RCOONa + NaOH \xrightarrow{CaO} R-H + Na_2CO_3\). The alkane formed has one carbon less than the original carboxylic acid.
Updated On: Apr 8, 2026
  • methane
  • ethene
  • propanoic acid
  • ethane
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the Concept:
Decarboxylation is the removal of CO\(_2\) from a carboxylic acid or its salt. Sodium salts of carboxylic acids on decarboxylation with soda lime (NaOH + CaO) yield alkanes.
Step 2: Detailed Explanation:
Sodium propionate is \(CH_3CH_2COONa\). Upon heating with soda lime, it undergoes decarboxylation: \[ CH_3CH_2COONa + NaOH \xrightarrow{CaO, \Delta} CH_3CH_3 + Na_2CO_3 \] The product is ethane.
Step 3: Final Answer:
Decarboxylation of sodium propionate gives ethane, option (D).
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