Question:

Correct formula of the complex formed in the brown ring test for nitrates is

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Brown ring test confirms presence of nitrate ion by formation of nitrosyl complex.
Updated On: Mar 19, 2026
  • FeSO₄ · NO
  • [Fe(H₂O)₅NO]²+
  • [Fe(H₂O)₅NO]⁺
  • [Fe(H₂O)₅NO]³+
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The Correct Option is C

Solution and Explanation

Step 1: Brown ring test involves formation of nitrosyl complex. Step 2: The complex formed is nitrosyl ferrous sulphate: [Fe(H₂O)₅NO]²+ But overall charge considering nitrate reaction is +1. Hence, correct complex is [Fe(H₂O)₅NO]⁺.
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