Question:

Consider the following statements concerning $N_2H_4$
1. It is an exothermic compound
2. It burns in air with the evolution of heat
3. It has kinetic stability
4. It reduces $Fe^{3+}$ to $Fe^{2+}$ in acidic medium
Which of the following combination is correct?

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Hydrazine's endothermic nature and high heat of combustion are why it is used as a high-performance rocket fuel.
Updated On: Apr 29, 2026
  • 2 and 3 are correct
  • 1 and 2 are correct
  • All are correct
  • 3 and 4 are correct
  • 2, 3 and 4 are correct
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The Correct Option is

Solution and Explanation

Concept: Hydrazine (\(N_2H_4\)) is a powerful reducing agent and a high-energy compound.

Step 1:
Evaluate Statement 1 and 2.
Hydrazine is actually an endothermic compound (\(\Delta H_f > 0\)), meaning it requires energy to form. However, it burns very easily in oxygen to release a massive amount of heat: \[ N_2H_4 + O_2 \rightarrow N_2 + 2H_2O + \text{Heat} \] Thus, 1 is False, 2 is True.

Step 2:
Evaluate Statement 3.
Despite being thermodynamically unstable (endothermic), it does not decompose instantly at room temperature. This is known as kinetic stability. (3 is True).

Step 3:
Evaluate Statement 4.
Hydrazine is a strong reducing agent. It readily reduces metal ions to lower oxidation states: \[ N_2H_4 + 4Fe^{3+} \rightarrow N_2 + 4H^+ + 4Fe^{2+} \] (4 is True).
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