Mechanistic link: Photosystem II houses the oxygen-evolving complex, a manganese cluster (\( \text{Mn}_4\text{CaO}_5 \)) that stores oxidising equivalents and splits water into oxygen, protons, and electrons.
When manganese is deficient, this cluster cannot assemble properly, so water-splitting and the resulting electron flow into the photosynthetic electron transport chain slow down, directly impairing photosynthesis, which is exactly the causal chain the assertion describes.
Because the reason identifies the precise biochemical site where manganese acts, it fully explains why its deficiency affects photosynthesis, so both statements are true and R explains A.