Concept:
Atomic number is defined as:
\[
\boxed{
\text{Number of protons present in the nucleus of an atom}
}
\]
Elements in the periodic table are arranged in increasing order of atomic number.
To arrange the given elements correctly, we first determine their atomic numbers.
Step 1: Find the atomic number of Scandium (\(\mathrm{Sc}\)).
Scandium has atomic number:
\[
\boxed{21}
\]
Thus:
\[
\mathrm{Sc} = 21
\]
Step 2: Find the atomic number of Vanadium (\(\mathrm{V}\)).
Vanadium has atomic number:
\[
\boxed{23}
\]
Thus:
\[
\mathrm{V} = 23
\]
Step 3: Find the atomic number of Manganese (\(\mathrm{Mn}\)).
Manganese has atomic number:
\[
\boxed{25}
\]
Thus:
\[
\mathrm{Mn} = 25
\]
Step 4: Find the atomic number of Nickel (\(\mathrm{Ni}\)).
Nickel has atomic number:
\[
\boxed{28}
\]
Thus:
\[
\mathrm{Ni} = 28
\]
Step 5: Arrange them in increasing order.
Now compare:
\[
21 < 23 < 25 < 28
\]
Substituting the symbols:
\[
\boxed{
\mathrm{Sc < V < Mn < Ni}
}
\]
Using the labels:
\[
\boxed{
B < A < C < D
}
\]
Step 6: Match with the options.
The correct option is:
\[
\boxed{(4)}
\]
Additional Understanding:
These elements belong to the first transition series.
Order in the periodic table:
\[
\mathrm{Sc,\ Ti,\ V,\ Cr,\ Mn,\ Fe,\ Co,\ Ni,\ Cu,\ Zn}
\]
Atomic number increases from left to right across a period.
Final Conclusion:
The increasing order of atomic number is:
\[
\boxed{
B < A < C < D
}
\]
Hence, the correct answer is:
\[
\boxed{(4)}
\]