Concept:
Carbocations are positively charged carbon species. Their stability depends mainly on the electron-donating effect of alkyl groups. Alkyl groups stabilize carbocations through the +I (inductive effect) and hyperconjugation.
Greater the number of alkyl groups attached to the positively charged carbon, greater is the stabilization.
Step 1: Identify the type of carbocations.
• Primary carbocation: carbon attached to one alkyl group
• Secondary carbocation: carbon attached to two alkyl groups
• Tertiary carbocation: carbon attached to three alkyl groups
Step 2: Apply stability rule.
More alkyl groups provide greater stabilization through inductive effect and hyperconjugation.
Step 3: Arrange them in increasing stability.
\[
\text{Primary}<\text{Secondary}<\text{Tertiary}
\]
\[
\boxed{\text{Primary<Secondary<Tertiary}}
\]