Question:

Anhydrous AlCl$_3$ fume in air due to:

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Anhydrous AlCl$_3$ fumes in air due to hydrolysis, reacting with moisture to form aluminum hydroxide and HCl.
Updated On: Apr 22, 2026
  • oxidation
  • hydrolysis
  • reduction
  • hydrogenation
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The Correct Option is B

Solution and Explanation

Step 1: Understand the behavior of anhydrous AlCl$_3$.
Anhydrous aluminum chloride (AlCl$_3$) is highly reactive and fume in moist air. It undergoes hydrolysis, where it reacts with water vapor in the air to form aluminum hydroxide and hydrochloric acid.

Step 2: Analyze the reactions.

- Oxidation: This involves the loss of electrons, which is not the case for anhydrous AlCl$_3$ in air.
- Hydrolysis: This is the correct reaction, where AlCl$_3$ reacts with water vapor to form Al(OH)$_3$ and HCl.
- Reduction: This involves the gain of electrons, but it is not the reaction for AlCl$_3$.
- Hydrogenation: This is the addition of hydrogen, which does not apply to AlCl$_3$.

Step 3: Conclusion.

The correct answer is (2), hydrolysis.
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