Let the momentum of the electron at any time \( t \) be \( p \), and its de-Broglie wavelength is \( \lambda \).
Then, the momentum is given by:
\( p = \frac{h}{\lambda} \)
The rate of change of momentum is:
\( \frac{dp}{dt} = -\frac{h}{\lambda^2} \frac{d\lambda}{dt} \)
Now, using \( ma = F \) (where \( m \) is the mass of the electron), we have:
\( ma = -\frac{h}{\lambda} \frac{d\lambda}{dt} \)
Where the negative sign represents a decrease in \( \lambda \) with time.
From the above equation:
\( ma = -\frac{h}{\left( \frac{h}{p} \right)^2} \frac{d\lambda}{dt} \)
Simplifying further:
\( a = -\frac{p^2}{mh} \frac{d\lambda}{dt} \)
\( a = -\frac{mv^2}{h} \frac{d\lambda}{dt} \)
From this, we can find:
\( \frac{d\lambda}{dt} = -\frac{ah}{mv^2} \quad \cdots (1) \)
Here, \( a = \frac{qE}{m} = \frac{e}{m} \frac{\sigma}{2\epsilon_0} \)
Also, \( v = u + at \), and since \( u = 0 \), we have:
\( v = at \)
Substituting the values of \( a \) and \( v \) in equation (1):
\( \frac{d\lambda}{dt} = -\frac{2h\epsilon_0}{\sigma e t^2} \)
Thus, we get:
\( \frac{d\lambda}{dt} \propto \frac{1}{t^2} \)
Therefore, \( n = 2 \)
Step 1: Determine the electric field and force on the electron.
- For an infinite non-conducting sheet with charge density \(-\sigma\), the electric field \(E\) is: \[ E = \frac{\sigma}{2\epsilon_0} \] - The force on the electron (charge \(-e\)) is: \[ F = -eE = -\frac{e\sigma}{2\epsilon_0} \] - The acceleration \(a\) of the electron is: \[ a = \frac{F}{m_e} = -\frac{e\sigma}{2\epsilon_0 m_e} \]
Step 2: Find the velocity as a function of time. - Since the electron starts from rest, its velocity \(v\) at time \(t\) is: \[ v = at = -\frac{e\sigma}{2\epsilon_0 m_e} t \]
Step 3: Express the de-Broglie wavelength \(\lambda\). - The de-Broglie wavelength is given by: \[ \lambda = \frac{h}{p} = \frac{h}{m_e v} = \frac{h}{m_e \left|\frac{e\sigma}{2\epsilon_0 m_e} t\right|} = \frac{2\epsilon_0 h}{e\sigma t} \]
Step 4: Compute the rate of change of \(\lambda\) with respect to time. \[ \frac{d\lambda}{dt} = -\frac{2\epsilon_0 h}{e\sigma t^2} \] - The magnitude of the rate of change is: \[ \left|\frac{d\lambda}{dt}\right| \propto \frac{1}{t^2} \]
Step 5: Compare with the given relation. - The problem states that \(\frac{d\lambda}{dt}\) varies inversely as the \(n^{th}\) power of time.
From Step 4, we see: \[ \left|\frac{d\lambda}{dt}\right| \propto \frac{1}{t^2} \quad \Rightarrow \quad n = 2 \]
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,


What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)