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an aromatic compound has molecular formula c h br
Question:
An aromatic compound has molecular formula C₇H₇Br. Give the possible isomers and the appropriate method to distinguish them.
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AgNO₃ test distinguishes: benzyl halides ≠ aryl halides
BITSAT - 2020
BITSAT
Updated On:
Mar 19, 2026
3 isomers; by heating with AgNO₃ solution
4 isomers; by treating with AgNO₃ solution
4 isomers; by oxidation
5 isomers; by oxidation
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Verified By Collegedunia
The Correct Option is
B
Solution and Explanation
Step 1:
Possible aromatic isomers of C₇H₇Br: • o-bromotoluene • m-bromotoluene • p-bromotoluene • benzyl bromide (C₆H₅CH₂Br)
Step 2:
Total isomers =4.
Step 3:
Distinction: • Benzyl bromide gives immediate precipitate with alcoholic AgNO₃ • Aryl bromides (o-, m-, p-) do not react
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