Step 1: Understanding the impedance in the L-C-R circuit.
In a series L-C-R circuit, the total impedance \( Z \) is given by:
\[
Z = \sqrt{R^2 + (X_L - X_C)^2},
\]
where \( X_L \) is the inductive reactance, \( X_C \) is the capacitive reactance, and \( R \) is the resistance. The potential difference across the capacitor \( V_C \) can be found using the voltage divider rule.
Step 2: Voltage divider rule.
The voltage across the capacitor is given by:
\[
V_C = \frac{X_C}{Z} V,
\]
where \( V \) is the total voltage across the series circuit, and \( Z \) is the total impedance.
Step 3: Use the given relationship \( X_L - X_C = R \).
We are given that \( X_L - X_C = R \). Therefore, the impedance simplifies to:
\[
Z = \sqrt{R^2 + R^2} = \sqrt{2} R.
\]
Step 4: Finding the r.m.s. value of potential difference.
The r.m.s. value of the potential difference is given by:
\[
V_{\text{rms}} = \frac{V_0}{\sqrt{2}}.
\]
Thus, the potential difference across the capacitor is:
\[
V_C = \frac{X_C}{Z} V_{\text{rms}} = \frac{X_C}{R} V_{\text{rms}} = \frac{V_0}{X_L}.
\]
Final Answer:
Thus, the r.m.s. value of the potential difference across the capacitor is:
\[
\boxed{\frac{V_0}{X_L}}.
\]